Five new coordination polymers of s- and d-block metals: Structural diversities, magnetic properties and luminescence

Five new coordination polymers of s- and d-block metals: Structural diversities, magnetic properties and luminescence
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s 区和 d 区金属的五种新型配位聚合物:结构多样性、磁性和发光

DOI:
10.1016/j.jssc.2018.12.026
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发表时间:
2019-02
影响因子:
3.3
通讯作者:
Yao-Yu Wang
Yao-Yu Wang
中科院分区:
化学3区
文献类型:
--
作者:
Yang Liu;Yong-Zhi Li;Ge Liu;Bin Liu;Lei Hou;Yao-Yu Wang

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为了探索金属离子控制合成配位聚合物(CPs)的方法,在反应过程中固定了温度和溶剂比。通过选择一系列s-和d-嵌段金属离子,用较少研究的草酸酰胺n′-双(4-邻苯二甲酸)(H4L)配体合成了[ZnL0.5(H2O)2]n(1)、[CoL0.5(H2O)2]n(2)、[Mn(H2L)(H2O)2]n(3)、[Ca(H2L)(H2O)2]n(4)和[Ba(H2L)(H2O)2]n(5)五个新的CPs。H4L表现出非常灵活的配位模式,形成了多种框架,包括基于M2O2cores(1和2)的2D同构网格状框架,基于1D [M(CO2)2]链(3和4)的同构4连接3D PtS框架,以及基于[BaO3]链(5.2和3)的2D波状层,分别显示出反铁磁性和铁磁性,而1、4和5具有强的固态发光。
In order to explore the metal ions-controlled syntheses of coordination polymers (CPs), the temperature and solvent ratio were fixed in the reaction processes. By selecting a series of s- and d-block metal ions, five new CPs, [ZnL0.5(H2O)2]n(1), [CoL0.5(H2O)2]n(2), [Mn(H2L)(H2O)2]n(3), [Ca(H2L)(H2O)2]n(4) and [Ba(H2L)(H2O)2]n(5), have been synthesized by employing a less-investigated oxalamideN,N′-bis(4-phthalic acid) (H4L) ligand. H4L shows very versatile coordination modes and leads to various frameworks, including isomorphous 2D grid-like layer based on M2O2cores for1and2, isomorphous 4-connected 3D PtS frameworks based on 1D [M(CO2)2]nchains for3and4, and a 2D wave-like layer based on [BaO3]nchains for5.2and3reveal the antiferromagnetic and ferromagnetic properties, respectively, while1,4and5possesses strong solid state luminescence.
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