X-ray Diffraction Imaging of Anatase and Rutile

X-ray Diffraction Imaging of Anatase and Rutile
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DOI:
10.1021/ac9024126
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发表时间:
2010-05-01
影响因子:
7.4
通讯作者:
Mizusawa, Mari
Mizusawa, Mari
中科院分区:
化学1区
文献类型:
--
作者:
Sakurai, Kenji;Mizusawa, Mari

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锐钛矿和金红石都是众所周知的 TiO2 稳定相。在现实样品中,TiO2 最有可能是这些相的混合物,而不是纯锐钛矿和金红石,因此定量分析极其重要。基本上可以利用晶体结构的差异通过X射线衍射(XRD)来确定平均比率,但是当尝试通过逐点扫描进行绘图时,这并不容易。本文介绍了新开发的投影式 XRD 成像的成功应用,这是一种极其快速且高效的方法。
Both anatase and rutile are well-known as stable phases of TiO2. In real-life samples, TiO2 is most likely to be a mixture of those phases rather than pure anatase and rutile, and therefore quantitative analysis is extremely important. It is basically possible to determine the average ratio by X-ray diffraction (XRD) using differences in the crystal structure, but it is not easy to do so when attempting mapping by point-by-point scanning. The present paper describes the successful application of newly developed projection-type XRD imaging, which is an extremely rapid and highly efficient method.