The stability of halide complexes of gallium
The stability of halide complexes of gallium
复制标题
镓卤化物配合物的稳定性
DOI：
10.1016/0013-4686(67)85004-7
复制
发表时间：
1967
影响因子：
6.6
通讯作者：
B. Andrews
中科院分区：
文献类型：
--
作者：
D. Morris;B. Andrews
用液体阳离子交换剂和~（72）Ga作示踪剂，测定了GaCl ~（2+）、GaBr ~（2+）和GaI ~（2+）形成的稳定常数。结果是指20°C和用高氯酸保持的0.691 M的离子强度。镓的阳离子卤代配合物，不像tetrahalogallates，似乎涉及离子键合，可能是外球型。
Stability constants for the formation of GaCl2+, GaBr2+and GaI2+have been measured by using a liquid cation exchanger and72Ga as a tracer. The results refer to 20°C and an ionic strength of 0·691 M maintained with perchloric acid. The cationic halocomplexes of gallium, unlike the tetrahalogallates, appear to involve ionic bonding and are probably of the outer sphere type.