Kinetic and Infrared Study of Photochromism of Metal Dithizonates
Kinetic and Infrared Study of Photochromism of Metal Dithizonates
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金属二硫腙酸盐光致变色的动力学和红外研究
DOI：
10.1021/ja00948a007
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发表时间：
1965
影响因子：
15
通讯作者：
N. Colthup
中科院分区：
文献类型：
--
作者：
L. Meriwether;E. Breitner;N. Colthup
在前文中，我们讨论了大量双硫腙金属配合物的光致变色和光化学行为。鉴于这些光致变色体系的独特性质，确定其活化形式的结构和反应机理是一个有意义的工作。为此，我们发展了一种跟踪复杂溶液在辐照下红外光谱变化的技术，
In the precedingpaper1 we discussed the photochromic and photochemical behavior of a large number of metal dithizonates. In view of the unique character-istics of these photochromic systems, it is of interest to determine thestructures of the activated forms of the complexes and the mechanisms of the reactionsinvolved. To this end a technique has beendeveloped for following the infrared spectralchanges of the com-plex solutions under irradiation, and a kinetic study of