An efficient catalyst system for palladium(0)-catalyzed cross-coupling of aryltrialkoxysilanes with aryl halides

An efficient catalyst system for palladium(0)-catalyzed cross-coupling of aryltrialkoxysilanes with aryl halides
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DOI:
10.1055/s-2005-922765
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发表时间:
2006-01-05
期刊:
影响因子:
2
通讯作者:
Masuda, Y
Masuda, Y
中科院分区:
化学4区
文献类型:
--
作者:
Murata, M;Yoshida, S;Masuda, Y

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Pd(Dba)(2)与双膦配体双(2-二异丙基膦苯基)醚的组合已被证明在氟化物诱导的芳基三烷氧基硅烷与芳基卤化物的交叉偶联中是普遍而有效的。底物范围很广,包括各种芳基溴化物和氯化物。
A combination of Pd(dba)(2) and a bisphosphine ligand, bis(2-diisopropylphosphinophenyl)ether, has proven to be general and efficient in fluoride-induced cross-coupling of aryltrialkoxysilanes with aryl halides. The substrate scope is broad and includes a variety of aryl bromides and chlorides.