The chirality, porosity, and ferromagnetism of a 3D nickel glutarate with intersecting 20-membered ring channels

The chirality, porosity, and ferromagnetism of a 3D nickel glutarate with intersecting 20-membered ring channels
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DOI:
10.1002/anie.200352520
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发表时间:
2003-01-01
影响因子:
16.6
通讯作者:
Férey, G
Férey, G
中科院分区:
化学1区
文献类型:
--
作者:
Guillou, N;Livage, C;Férey, G

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图2. a)Ni 1(淡紫色)和Ni 2(淡蓝色)交替的四个螺旋视图,由Ni 2八面体(绿色)连接,B)具有两个独立戊二酸根离子的波纹状二十元环的多面体视图;橙子离子无序,统计占有率为2/3,c)镍网络视图,显示互连环,d)氧化镍隧道视图[111]。
Figure 2. a) View of four helixes with alternating Ni1 (mauve) and Ni2 (pale blue) connected by Ni2 octahedra (green), b) polyhedral view of a corrugated twenty-membered ring with the two independent glutarate ions; the orange one is disordered with statistic occupancy of 2/3, c) view of the nickel network showing interconnected rings, d) view of the nickel oxide tunnels down [111].