NMR Chemical Shifts of Trace Impurities: Common Laboratory Solvents, Organics, and Gases in Deuterated Solvents Relevant to the Organometallic Chemist
NMR Chemical Shifts of Trace Impurities: Common Laboratory Solvents, Organics, and Gases in Deuterated Solvents Relevant to the Organometallic Chemist
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DOI：
10.1021/om100106e
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发表时间：
2010-05-10
期刊：
影响因子：
2.8
通讯作者：
Goldberg, Karen I.
中科院分区：
文献类型：
--
作者：
Fulmer, Gregory R.;Miller, Alexander J. M.;Goldberg, Karen I.
已编制了常见有机化合物的H-1和C-13核磁共振化学移动表，这些有机化合物通常用作试剂或在重氢有机溶剂中作为产物或污染物被发现。根据Gottlieb、Kotlyar和Nudelman在《有机化学杂志》上的工作，常见杂质的信号现在报告在其他核磁共振溶剂(四氢呋喃-d(8)、甲苯-d(8)、二氯甲烷-d(2)、氯苯-d(5)和2，2，2-三氟乙醇-d(3))中，这些溶剂经常在有机金属实验室中使用。还报告了所有列出的溶剂中经常用作试剂或内标或在有机金属化学中发现为产物的其他有机物的化学位移。
Tables of H-1 and C-13 NMR chemical shifts have been compiled for common organic compounds often used as reagents or found as products or contaminants in deuterated organic solvents. Building upon the work of Gottlieb, Kotlyar, and Nudelman in the Journal of Organic Chemistry, signals for common impurities are now reported in additional NMR solvents (tetrahydrofuran-d(8), toluene-d(8), dichloromethane-d(2), chlorobenzene-d(5), and 2,2,2-trifluoroethanol-d(3)) which are frequently used in organometallic laboratories. Chemical shifts for other organics which are often used as reagents or internal standards or are found as products in organometallic chemistry are also reported for all the listed solvents.