[VO(H2O)5]H[PMo12O40]-catalyzed nitration of alkanes with nitric acid.

[VO(H2O)5]H[PMo12O40]-catalyzed nitration of alkanes with nitric acid.
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DOI:
10.1039/b314978a
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发表时间:
2004-02
影响因子:
4.9
通讯作者:
K. Yamaguchi;Satoshi Shinachi;N. Mizuno
K. Yamaguchi;Satoshi Shinachi;N. Mizuno
中科院分区:
化学2区
文献类型:
--
作者:
K. Yamaguchi;Satoshi Shinachi;N. Mizuno

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[VO(H2O)5]H[PMo12O40]含有钒基阳离子和PMo12O40(3-),在356k的乙酸中以硝酸为硝化剂,可作为包括烷基苯在内的各种烷烃的硝化催化剂。
[VO(H2O)5]H[PMo12O40], which contains vanadyl counter cations and PMo12O40(3-), can act as a catalyst for the nitration of various alkanes including alkylbenzenes using nitric acid as a nitrating agent in acetic acid at 356 K.