In-situ synthesis of nanocomposite from metal-organic frameworks template for high-performance rechargeable batteries

In-situ synthesis of nanocomposite from metal-organic frameworks template for high-performance rechargeable batteries
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用于高性能可充电电池的金属有机框架模板原位合成纳米复合材料

DOI:
10.1016/j.jpowsour.2020.228247
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发表时间:
2020-07
影响因子:
9.2
通讯作者:
Jian-Jun Liu
Jian-Jun Liu
中科院分区:
工程技术2区
文献类型:
--
作者:
Shu-Biao Xia;Yu-Xing Yan;Wen-Jin Huang;Rui-Ming Yang;Hongbo Suo;Jia-Ming Liu;Fei-Xiang Cheng;Jian-Jun Liu

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Metal-organic frameworks (MOFs) as a new type of hybrid material assembled with metallic ions and organic ligands, is useful precursors or templates for the construction of various materials. MOFs derivatives show excellent performance as Li ion batteries (LIBs) electrodes or catalytic materials. Herein, we report a convenient, straightforward one-pot preparation of tin oxides nanoparticles confined in porous carbon matrices by carbonizing Sn-based MOFs. The as-prepared SnO2/SnO@C electrode show excellent cycling electrochemical and rate properties. It delivers an initial specific capacity of 1567.1 mA h g−1at 100 mA g−1current density as well as a remarkably enhanced cycle performance. Density functional theory (DFT) theoretical calculations,ex-situX-ray diffraction (XRD) and X-ray photoelectron spectra (XPS) further reveal the lithium storage mechanism of SnO2/SnO@C electrodes. These results demonstrate that as-synthesized SnO2/SnO@C composite is a promising anode material for LIBs.
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