Templated synthesis of diluted magnetic semiconductors using transition metal ion-doped metal-organic frameworks: the case of Co-doped ZnO
Templated synthesis of diluted magnetic semiconductors using transition metal ion-doped metal-organic frameworks: the case of Co-doped ZnO
复制标题
使用过渡金属离子掺杂金属有机框架模板合成稀磁性半导体：以钴掺杂 ZnO 为例
DOI：
10.1039/c5ce02488a
复制
发表时间：
2016-01-01
期刊：
影响因子：
3.1
通讯作者：
Zheng, Lansun
中科院分区：
文献类型：
--
作者：
Lue, Yinyun;Zhou, Qi;Zheng, Lansun
At present, the deliberate and controlled doping of transition metal ions in semiconductor hosts remains a challenge for the development of diluted magnetic semiconductors (DMSs) with room-temperature ferro-magnetic properties. In this work, Co-doped ZnO (Zn1-xCoxO, x = 0.03, 0.05, and 0.10) with different Co doping concentrations were successfully prepared via a simple thermal decomposition process using Co-doped Zn-containing metal-organic frameworks as precursors. X-ray diffraction and Raman scattering studies confirmed the incorporation of Co into the ZnO lattices. X-ray photoelectron spectroscopy indicated that the substituted Co ions were in the 2+ oxidation state and were incorporated at Zn2+ sites. The as-prepared Co-doped ZnO samples displayed an extended light absorption range compared to pure ZnO and were ferromagnetic at room temperature. Given the widely tunable range of the doping concentrations used and the abundance of metal-organic framework resources, the proposed synthetic strategy is potentially applicable to the fabrication of other transition metal ion-doped DMSs.
