Electrochemical Coupling Layer-by-layer (ECC-LbL) Assembly in Patterning Mode
Electrochemical Coupling Layer-by-layer (ECC-LbL) Assembly in Patterning Mode
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DOI：
10.1246/cl.2012.383
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发表时间：
2012-04-05
影响因子：
1.6
通讯作者：
Ariga, Katsuhiko
中科院分区：
文献类型：
--
作者：
Li, Mao;Ishihara, Shinsuke;Ariga, Katsuhiko
功能性结构单元（富勒烯和芴）集成到多层膜中，通过利用电化学耦合层-层（ECC-LbL）组装驱动的共价碳-碳耦合反应的烷基咔唑侧基。图案化模式中的ECC-LbL组装件可用于局部地修饰功能单元，并且在此已在图案化荧光显示器中得到证明。ECC-LbL是一种多功能的表面加工方法，在许多应用中具有很好的潜力。
Functional building blocks (fullerene and fluorene) were integrated into multilayers by utilizing electrochemical coupling layer-by-layer (ECC-LbL) assembly driven by the covalent carbon carbon coupling reaction of pendant alkylcarbazoyl groups. The ECC-LbL assembly in patterning mode can be used to locally immobilize functional units and has been demonstrated here in a patterned fluorescent display. ECC-LbL is a versatile method for surface fabrication with promising potential in many applications.