Thermodynamic Assessment of the Ag-Cu-O System

Thermodynamic Assessment of the Ag-Cu-O System
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Ag-Cu-O 体系的热力学评估

DOI:
10.1361/105497198770342085
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发表时间:
1998
期刊:
Journal of Phase Equilibria
影响因子:
--
通讯作者:
L. Gauckler
L. Gauckler
中科院分区:
--
文献类型:
--
作者:
J. Assal;B. Hallstedt;L. Gauckler

文献摘要

被引文献

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对Ag-Cu-O体系的实验数据进行了综述,并提出了优化的热力学描述。Ag-Cu-O系统不包含任何三元固相,并且其特征在于液态金属相和液态氧化物相之间的可熔性间隙。通过热力学评估很好地描述了少量的实验数据。液相描述的离子液体的两个亚晶格模型和相关的溶液模型进行了比较。
Available experimental data on the Ag-Cu-O system have been reviewed and an optimized thermodynamic description is presented. The Ag-Cu-O system does not contain any ternary solid phases and is characterized by a miscibility gap between the liquid metal phase and the liquid oxide phase. The few experimental data are well described by the thermodynamic assessment. The liquid phase is described by the two-sublattice model for ionic liquids and a comparison is made with the associated solution model.