Two stable hydrides of antimony:: RSbH2 and R(H)Sb-Sb(H)R (R = (Me3Si)2CH)

Two stable hydrides of antimony:: RSbH2 and R(H)Sb-Sb(H)R (R = (Me3Si)2CH)
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DOI:
10.1021/om010177h
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发表时间:
2001-06-25
期刊:
影响因子:
2.8
通讯作者:
Offermann, W
Offermann, W
中科院分区:
化学2区
文献类型:
--
作者:
Balázs, G;Breunig, HJ;Offermann, W

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通过RSbCl_2与LiAlH_4反应,以良好的产率生成RSbH_2(1)和R(H)Sb-Sb(H)R(2)(R =(Me_3Si)(2)CH)。2的晶体结构由内消旋形式的分子组成。
RSbH2 (1) and R(H)Sb-Sb(H)R (2) (R = (Me3Si)(2)CH) are formed in good yield by reactions of RSbCl2 with LiAlH4. The crystal structure of 2 consists of molecules in the meso form.