Ultrasound in polymer chemistry: Revival of an established technique
Ultrasound in polymer chemistry: Revival of an established technique
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DOI：
10.1002/pola.21646
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发表时间：
2006-10-01
影响因子：
--
通讯作者：
Sijbesma, Rint P.
中科院分区：
文献类型：
--
作者：
Paulusse, Jos M. J.;Sijbesma, Rint P.
超声波在聚合物化学中的应用历史可以追溯到很久以前。最初，它的用途仅限于作为一种通过溶剂分解形成自由基或通过聚合物断裂导致自由基的引发自由基聚合的替代方法。最近，超声波的原始力量已经通过使用聚合物链中的弱键来集中，这使得能够产生定义明确的大自由基和配位不饱和金属配合物。(c) 2006 Wiley期刊公司
The history of ultrasound in polymer chemistry Goes back a ton way. Initially, its uses were limited to being an alternative method of initiating radical polymerizations through the decomposition of solvents to form radicals or through the breakage of polymers leading to macroradicals. Recently, the raw power of ultrasound has been focused through the use of weak linkages in polymer chains, which enables the production of well-defined macroradicals and coordinatively unsaturated metal complexes. (c) 2006 Wiley Periodicals, Inc.