Synthesis, Spectroscopic Properties and Single Crystal X-ray Structure of Dithiocyanato-N-bis[8-(diphenylphosphino)-quinoline]ruthenium(II)
Synthesis, Spectroscopic Properties and Single Crystal X-ray Structure of Dithiocyanato-N-bis[8-(diphenylphosphino)-quinoline]ruthenium(II)
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二硫氰基-N-双[8-(二苯基膦)-喹啉]钌(II)的合成、光谱性质及单晶X射线结构
DOI：
10.47014/17.2.3
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发表时间：
2022
影响因子：
0.4
通讯作者：
Lynnette Cary
中科院分区：
文献类型：
--
作者：
Kimberly J. Jurgensen;W. Skinner;B. Oronsky;Nacer D. Abrouk;A. E. Graff;R. Landes;William E. Culp;T. Summers;Lynnette Cary
合成了一种新的钌配合物[Ru（N-P）2（SCN）2]，其中N-P = 8-（二苯基膦基）喹啉，并通过红外光谱、紫外-可见光谱和X射线单晶衍射对其进行了表征。该配合物属于单斜晶系，空间群为P1211。晶胞参数为：a = 9.9635（7）Ω，B = 18.8967（9）Ω，c = 11.2651（6）Ω，α = γ = 90 Ω，β = 110.474（7）Ω。配合物具有畸变的八面体结构，硫氰酸根为顺式构型。键长分析表明，反式影响的顺序为：P > N（SCN-）> N（喹诺酮）。
The new ruthenium complex, [Ru(N-P)2(SCN)2], where N-P = 8-(diphenylphosphino)quinoline, was prepared and characterized by FT-IR, UV-Vis spectrometry and X-ray crystallography. The complex crystallized in the monoclinic system with the space group P1211. The cell parameters are a = 9.9635(7) Å, b = 18.8967(9) Å, c = 11.2651(6) Å, α = γ = 90, β = 110.474(7) . The complex has a distorted octahedral structure with cis configuration for the thiocyanate groups. The bond-length analysis indicates the following order of trans-influence: P > N(SCN-) > N(quinolone).