Synthesizing amphiphilic block copolymers through macromolecular azo-coupling reaction.
Synthesizing amphiphilic block copolymers through macromolecular azo-coupling reaction.
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DOI：
10.1039/c1cc16362k
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发表时间：
2012-01
影响因子：
4.9
通讯作者：
Yaning He;Wei He;R. Wei;Zhen Chen;Xiaogong Wang
中科院分区：
文献类型：
--
作者：
Yaning He;Wei He;R. Wei;Zhen Chen;Xiaogong Wang
报道了一种合成两亲性嵌段共聚物的新方法。通过偶氮偶联反应，将苯胺官能化PEG的重氮盐与具有适合偶氮偶联反应的末端的聚合物嵌段进行偶氮偶联反应，合成了具有明确结构的共聚物。
This communication reports a new approach to synthesize amphiphilic block copolymers. The copolymers with well-defined structures were synthesized by macromolecular azo-coupling reaction between the diazonium salt of aniline-functionalized PEG and the polymeric blocks with a terminal suitable for the azo-coupling reaction.