Two types of new polymeric copper(I) complexes of pyrazinecarboxamide having channel and helical structures
Two types of new polymeric copper(I) complexes of pyrazinecarboxamide having channel and helical structures
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DOI：
10.1021/ic970427f
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发表时间：
1997-11-05
影响因子：
4.6
通讯作者：
Kitagawa, S
中科院分区：
文献类型：
--
作者：
Munakata, M;Wu, LP;Kitagawa, S
报道了2-吡嗪甲酰胺铜（I）配合物[Cu_2（pzca）_3]（ClO_4）_2（Me_2CO）_2（1）和[Cu（pzca）（Me_2CO）_（0.5）]（BF_4）（2）的合成和结构。配合物形成不寻常的通道或螺旋结构的基础上的配体桥接的Cu（I）离子的六核圆形阵列，是目前感兴趣的合成，大孔配位固体的设计。
The syntheses and structures of two polymeric copper(I) complexes of 2-pyrazinecarboxamide, [Cu2(pzca)3](ClO4)2(Me2CO)2(1) and [Cu(pzca)(Me2CO)0.5](BF4) (2), are reported. The complexes form unusual channel or helical structures based on the hexanuclear circular array of ligand-bridged Cu(I) ions that are of current interest in the design of synthetic, macroporous coordination solids.