Metallonaphthalocyanines as triplet sensitizers for near-infrared photon upconversion beyond 850 nm

Metallonaphthalocyanines as triplet sensitizers for near-infrared photon upconversion beyond 850 nm
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DOI:
10.1039/c5cp02733k
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发表时间:
2015-01-01
影响因子:
3.3
通讯作者:
Kimizuka, Nobuo
Kimizuka, Nobuo
中科院分区:
化学2区
文献类型:
--
作者:
Amemori, Shogo;Yanai, Nobuhiro;Kimizuka, Nobuo

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在基于三重态-三重态湮灭的光子上转换(TTA-UC)中,波长大于850 nm的近红外(NIR)光的利用仍然是一个突出的问题。我们通过使用金属酞菁作为三重致敏剂实现了这一点;在近红外光(856 nm)激发下,在可见光范围内观察到上转换发射,具有良好的光稳定性。
In triplet-triplet annihilation-based photon upconversion (TTA-UC), the utilization of near-infrared (NIR) light with a wavelength longer than 850 nm remains an outstanding issue. We realized this by employing metallonaphthalocyanines as triplet sensitizers; upon excitation of NIR light (856 nm), upconverted emission was observed in the visible range with remarkable photostability.