Peroxide route to pentaoxyphosphoranes
Peroxide route to pentaoxyphosphoranes
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生成五氧基正膦的过氧化物路线
DOI：
10.1021/ja01049a020
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发表时间：
1969
影响因子：
15
通讯作者：
Donald H. Jones
中科院分区：
文献类型：
--
作者：
D. B. Denney;Donald H. Jones
通过使三取代亚磷酸盐与过氧化二乙酯反应，制备了多种五氧磷烷。在一种情况下，同样的五氧磷是由ß-萘醌和三乙基亚磷酸酯缩合而成，并由亚磷酸酯3与过氧化二乙酯反应而成。得到了五氧磷烷的相对生成速率与结构的函数关系。含有五氧磷烷的五元环在立体定向过程中分解得到环氧化物。
A variety of pentaoxyphosphoranes have been prepared by allowing trisubstituted phosphites to react with diethyl peroxide. In one case the same pentaoxyphosphorane was prepared by condensation of ß-naphthoquinone and triethyl phoshite and by reaction of the phosphite, 3, with diethyl peroxide. The relative rates of formation of the pentaoxyphosphoranes have been obtained as a function of structure. Decomposition of fivemembered ring containing pentaoxyphosphoranes gives epoxides in a stereospecific process.