MÖSSBAUER STUDIES OF BRIDGED FERROCENOPHANE DERIVATIVE’S POLYIODIDES
MÖSSBAUER STUDIES OF BRIDGED FERROCENOPHANE DERIVATIVE’S POLYIODIDES
复制标题
桥联二茂铁衍生物多碘化物的穆斯堡尔研究
DOI：
10.1246/cl.1983.1775
复制
发表时间：
1983
影响因子：
1.6
通讯作者：
H. Sano
中科院分区：
文献类型：
--
作者：
Masanobu Watanabe;Kumiko Sato;I. Motoyama;H. Sano
[2]二茂铁衍生物在苯中与碘氧化，并用穆斯堡尔光谱对其进行了研究。在78 K时，化合物的四极分裂值为3.70 mm−1，是二茂铁衍生物中发现的最大的四极分裂值之一，表明铁原子和碘原子之间存在强烈的直接相互作用。结果与[3]和[4]二茂铁多碘化物进行了比较。
[2]Ferrocenophanes, the ring tilted ferrocene derivatives, were oxidized with iodine in benzene and studied by means of Mossbauer spectroscopy. The quadrupole splitting value of the compounds is found to be 3.70 mms−1 at 78 K, which is one of the largest found in ferrocene derivatives, suggesting the presence of a strong direct interaction between iron atoms and iodine atoms. The results were compared with [3] and [4] ferrocenophane’s polyiodides.