Dual aminoquinolate diarylboron and nickel catalysed metallaphotoredox platform for carbon-oxygen bond construction.
Dual aminoquinolate diarylboron and nickel catalysed metallaphotoredox platform for carbon-oxygen bond construction.
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DOI：
10.1039/d0cc03230a
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发表时间：
2020-06
影响因子：
4.9
通讯作者：
Weisai Zu;Craig S. Day;Lanfeng Wei;X. Jia;Liang Xu
中科院分区：
文献类型：
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作者：
Weisai Zu;Craig S. Day;Lanfeng Wei;X. Jia;Liang Xu
在此，氨基喹啉二芳基硼配合物在双Ni/光氧化还原催化的碳-氧构建反应中用作光催化剂。通过这个统一的金属光氧化还原平台，不同的（杂）芳基卤化物可以方便地与酸、醇和水偶联。该方法操作简单、底物范围广、官能团兼容性好。
Herein, aminoquinolate diarylboron complexes are utilized as photocatalysts in dual Ni/photoredox catalyzed carbon-oxygen construction reactions. Via this unified metallaphotoredox platform, diverse (hetero)aryl halides can be conveniently coupled with acids, alcohols and water. This method features operational simplicity, broad substrate scope and good compatibility with functional groups.