Chemospecific Allylation and Domino Metathesis of 7-Oxanorbornenes for Skeletal and Appendage Diversity
Chemospecific Allylation and Domino Metathesis of 7-Oxanorbornenes for Skeletal and Appendage Diversity
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DOI：
10.1002/ejoc.200800781
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发表时间：
2009-01-01
影响因子：
2.8
通讯作者：
Sasaki, Makoto
中科院分区：
文献类型：
--
作者：
Ikoma, Minoru;Oikawa, Masato;Sasaki, Makoto
我们报告了一种基于串联Ugi/Diels-Alder反应，然后进行多米诺复分解的具有附属物多样性的多元杂环化合物的合成策略。的关联效应的酰胺羰基功能的钌金属中心提出，以占的差异，在复分解产率。((C)Wiley-VCH Verlag GmbH & Co. KGaA，69451魏因海姆，德国，2009）
We report a synthetic strategy for skeletally diverse heterocycles featuring appendage diversity based on a tandem Ugi/Diels-Alder reaction followed by domino metathesis. An associating effect of the amide carbonyl functionality to the ruthenium metal center is proposed in order to account for the difference in the metathesis yields. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)