Effect of fluorine doping on the optical and mechanical properties of bismuth-containing silicate and borate glasses

Effect of fluorine doping on the optical and mechanical properties of bismuth-containing silicate and borate glasses
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氟掺杂对含铋硅酸盐和硼酸盐玻璃光学和机械性能的影响

DOI:
10.1007/s10854-021-07508-8
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发表时间:
2022
期刊:
J. Mater. Sci.: Mater. Electron.
影响因子:
--
通讯作者:
and A. Saitoh
and A. Saitoh
中科院分区:
--
文献类型:
--
作者:
K. Hayashi;T. Shimizu;S. Matsuishi;H. Hiramatsu;and A. Saitoh

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研究了氟掺杂对二元Bi 2 O3-SiO2和Bi 2 O3-B2 O3玻璃的光学带隙和杨氏模量的影响。无色的Bi 2 O3-BiF 3-SiO2和Bi 2 O3-BiF 3-B2 O3玻璃与纯石英玻璃相比具有非常小的光弹性和弹性常数,在可见光范围内使用偏振控制的光学元件的开发中是含铅氧化物玻璃的潜在替代品。氟掺杂的影响进行了总结,蓝移的光学带隙高达~ 0.3 eV的~ 3.6 eV。所施加的光弹性常数保持在±(0.02-0.07)× 10− 12 Pa −1,掺杂后的杨氏模量约为70 GPa。然而,没有决定性的连接,氟掺杂的结构效果,通过傅里叶变换红外和拉曼散射光谱检查,虽然有明确的证据表明,宽的光学带隙,非常小的光弹性常数,和大的弹性常数的兼容性。
We investigate the effect of fluorine doping on the optical bandgap and Young’s modulus of binary Bi2O3–SiO2and Bi2O3–B2O3glasses. Colorless Bi2O3–BiF3–SiO2and Bi2O3–BiF3–B2O3glasses, with very small photoelasticity and elastic constants compared with pure silica glass, are potential alternatives to lead-containing oxide glass in the development of optical components using polarization control in the visible wavelength range. The effects of fluorine doping are summarized for blueshifts in the optical bandgaps of up to ~ 0.3 eV from ~ 3.6 eV. The applied photoelastic constants remained small at ± (0.02–0.07) × 10−12Pa−1, and the Young’s moduli were ~ 70 GPa after doping. However, no conclusive connection to the structural effect of fluorine doping, as examined by Fourier-transform infrared and Raman scattering spectroscopies, was made, although there is clear evidence of the compatible properties of wide optical bandgap, very small photoelastic constant, and large elastic constant.
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