Synthesis of 5-alkyl-1-aryl-4,4-dimethyl-2,6,7-trioxabicyclo[3.3.0]heptanes as a chemiluminescent substrate with remarkable thermal stability
Synthesis of 5-alkyl-1-aryl-4,4-dimethyl-2,6,7-trioxabicyclo[3.3.0]heptanes as a chemiluminescent substrate with remarkable thermal stability
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DOI：
10.1016/s0040-4039(97)00483-8
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发表时间：
1997-04-21
影响因子：
1.8
通讯作者：
Tadokoro, K
中科院分区：
文献类型：
--
作者：
Matsumoto, M;Watanabe, N;Tadokoro, K
合成了各种1-aryl-4，4-dimethyl-2，6，7-trioxabicyclo[3.2.0]heptanes，并对其热稳定性和F诱导化学发光性能进行了研究。在本文合成的双环二氧杂环烷中，5-位含有叔丁基或9-甲基荧基的双环二氧杂环烷具有显著的热稳定性。(C)1997年爱思唯尔科学有限公司。
Various 1-aryl-4,4-dimethyl-2,6,7-trioxabicyclo[3.2.0]heptanes were synthesized and their thermal stabilities and F--induced chemiluminescent properties were examined. Among the bicyclic dioxetanes synthesized here, one bearing a tert-butyl or a 9-methylfluorenyl at the 5-position exhibited remarkable thermal stability. (C) 1997 Elsevier Science Ltd.