Furostanol saponins from Allium tuberosum

Furostanol saponins from Allium tuberosum
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DOI:
10.1016/s0031-9422(99)00312-x
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发表时间:
1999-12-01
期刊:
影响因子:
3.8
通讯作者:
Chen, ZL
Chen, ZL
中科院分区:
生物学2区
文献类型:
--
作者:
Sang, SM;Lao, AN;Chen, ZL

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从大葱种子中分离得到3个新的呋喃甾醇皂苷,即块茎皂苷A、块茎皂苷B和块茎皂苷C。根据化学反应和光谱数据,确定其结构为26-O-β-D-吡喃葡萄糖基-(25 S)-5α-呋喃-20(22)-烯-2α,3β,26-三醇3-O-α-L-鼠李糖-(1-)-O-β-D-吡喃葡萄糖苷,26-O-β-D-吡喃葡萄糖苷-(25 S)-5α-呋喃-20(22)-烯-2α,3β,26-三醇3-O-α-L-鼠李糖-(1-GT;2)-[α-L-鼠李糖基-(1->4)]-β-D-吡喃葡萄糖苷和26-O-β-D-吡喃葡萄糖苷-(25 S)-5α-呋喃-20(22)-烯-2α,3β,26-三醇3-O-α-L-鼠李糖基-(1->2)-[β-D-吡喃葡萄糖苷-(1->3)]-β-D-吡喃葡萄糖苷。(C)1999爱思唯尔科学有限公司。保留所有权利。
Three new furostanol saponins, tuberoside A, B and C, have been isolated from the seeds of Allium tuberosum. On the basis of chemical reactions and spectral data, their structures were established as 26-O-beta-D-glucopyranosyl-(25 S)-5 alpha-furost-20(22)-ene-2 alpha,3 beta,26-triol 3-O-alpha-L-rhamnopyranosyl-(1 --> 2)-O-beta-D-glucopyranoside; 26-O-beta-D-glucopyranosyl-(25 S)-5 alpha-furost-20(22)-ene-2 alpha,3 beta,26-triol 3-O-alpha-L-rhamnopyranosyl-(1 --> 2)-[alpha-L-rhamnopyranosyl-(1 --> 4)]-beta-D-glucopyranoside and 26-O-beta-D-glucopyranosyl-(25 S)-5 alpha-furost-20(22)-ene-2 alpha,3 beta,26-triol 3-O-alpha-L-rhamnopyranosyl-(1 --> 2)-[beta-D-glucopyranosyl-(1 -->3)]-beta-D-glucopyranoside, respectively. (C) 1999 Elsevier Science Ltd. All rights reserved.