Conformational analysis of chiral helical perfluoroalkyl chains by VCD

Conformational analysis of chiral helical perfluoroalkyl chains by VCD
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DOI:
10.1021/ja0602041
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发表时间:
2006-05-10
影响因子:
15
通讯作者:
Inabe, Tamotsu
Inabe, Tamotsu
中科院分区:
化学1区
文献类型:
--
作者:
Monde, Kenji;Miura, Nobuaki;Inabe, Tamotsu

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振动圆二色性(VCD)技术借助理论计算成功地揭示了溶液中全氟烷基链偏螺旋的绝对构型,并得到了x射线晶体学研究的支持。
Vibrational circular dichroism (VCD) technique successfully revealed the absolute configuration of the biased helix of perfluoroalkyl chains in solution with the aid of theoretical calculations, which was supported by an X-ray crystallographic study.