Azo Compounds as Active Materials of Energy Storage Systems
Azo Compounds as Active Materials of Energy Storage Systems
复制标题
偶氮化合物作为储能系统的活性材料
DOI：
10.1002/anie.202206093
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发表时间：
2022
期刊：
影响因子：
--
通讯作者：
Yoshikawa Hirofumi
中科院分区：
文献类型：
--
作者：
Shimizu Takeshi;Tanifuji Naoki;Yoshikawa Hirofumi
电力设备的快速发展和对可持续能源供应的不断增长的需求需要高性能储能系统的发展，如可充电和氧化还原液流电池。然而，这些电池通常含有无机活性材料，这表现出几个阻碍进一步发展的关键缺陷。在这方面，偶氮化合物是很有前途的替代品，具有快速动力学、多电子氧化还原反应和可调（通过结构调整）电池性能的优点。本文综述了偶氮化合物作为可充电和氧化还原液流电池活性材料的应用，讨论了材料设计和电化学反应机理等方面的问题，并总结了相应的研究前景和研究方向，以促进该领域的进一步发展。
The rapid evolution of electrical devices and the increasing demand for the supply of sustainable energy necessitate the development of high‐performance energy storage systems such as rechargeable and redox flow batteries. However, these batteries typically contain inorganic active materials, which exhibit several critical drawbacks hindering further development. In this regard, azo compounds are promising alternatives, offering the benefits of fast kinetics, multi‐electron redox reactions, and tunable (via structural adjustment) battery performance. Herein, we review the use of azo compounds as the active materials of rechargeable and redox flow batteries, discuss certain aspects of material design and electrochemical reaction mechanisms, and summarize the corresponding perspectives and research directions to facilitate further progress in this field.