Controllable processes for generating large single crystals of poly(3-hexylthiophene).
Controllable processes for generating large single crystals of poly(3-hexylthiophene).
复制标题
DOI：
10.1002/anie.201205653
复制
发表时间：
2012-10
影响因子：
--
通讯作者：
K. Rahimi;I. Botiz;N. Stingelin;N. Kayunkid;M. Sommer;F. Koch;H. Nguyen;O. Coulembier;P. Dubois;M. Brinkmann;G. Reiter
中科院分区：
文献类型：
--
作者：
K. Rahimi;I. Botiz;N. Stingelin;N. Kayunkid;M. Sommer;F. Koch;H. Nguyen;O. Coulembier;P. Dubois;M. Brinkmann;G. Reiter
播种种子：一个简单的策略的基础上自播种允许大单晶的长regioregular聚（3-己基噻吩）链从溶液中生长。当适当结晶时，区域规整度和分子量不同的材料形成具有交叉己基侧基的单斜晶型II晶体（见图）。
Sowing the seeds: A simple strategy based on self-seeding allows large single crystals of long regioregular poly(3-hexylthiophene) chains to be grown from solution. When appropriately crystallized, materials differing in their degrees of regioregularity and molecular weights formed monoclinic form II crystals with interdigitated hexyl side groups (see picture).