Transition- metal- free amination phosphoryl azide for the synthesis of phosphoramidates
Transition- metal- free amination phosphoryl azide for the synthesis of phosphoramidates
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DOI：
10.1039/c9ra03389k
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发表时间：
2019-05-29
期刊：
影响因子：
3.9
通讯作者：
Chen, Xiuling
中科院分区：
文献类型：
--
作者：
Li, Qing;Sun, Xiaohua;Chen, Xiuling
通过磷酰叠氮的胺化反应，发展了一种简便、有效的氨基磷酸酯合成方法。在温和的反应体系下，一步合成了多种氨基磷酸酯，产率较高。该方法使用容易获得的胺作为N源，并提供了P-N键形成的新机会。
A facile and efficient approach to phosphoramidates was developed via amination of phosphoryl azides. A variety of phosphoramidates were obtained in one step with good to excellent yields under a mild reaction system. The process uses easily available amines as a N source and offers a new opportunity for P-N bond formation.