Two Examples of Molecular Semiconductors: Phthalocyanine Complexes of Lithium and Lutetium
Two Examples of Molecular Semiconductors: Phthalocyanine Complexes of Lithium and Lutetium
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分子半导体的两个例子：锂和镥的酞菁络合物
DOI：
10.1080/00268948808070256
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发表时间：
1988
期刊：
影响因子：
--
通讯作者：
M. Maitrot
中科院分区：
文献类型：
--
作者：
P. Turek;P. Petit;J. André;J. Simon;R. Even;B. Boudjema;G. Guillaud;M. Maitrot
“分子半导体”一词从未有过明确的定义。提出了以下标准：(i)它是由可以单独合成的分子单元组成的分子材料；（ii）它的固有电导率在10−6-10−1Ω−1 cm−1范围内；（iii）它可以掺杂电子给体和/或电子受体，形成n或p掺杂材料。本文讨论了酞菁锂和双酞菁镥在本征和外征导电范围内的电学性质。
Abstract The designation “molecular semiconductor” has never received any clear cut definition. The following criteria are proposed: (i) it is a molecular material constituted of molecular units which can be individually synthesized (ii) its intrinsic conductivity is in the range 10−6-10−1Ω−1 cm−1 (iii) it can be doped with electron donors and/or electron acceptors to form n-or p-doped materials. This paper deals with the description of the electrical properties of lithium phthalocyanine PcLi and lutetium bisphthalocyanine Pc2Lu, in the intrinsic and extrinsic conduction ranges.