Ultrafast Grignard addition reactions in the presence of water.
Ultrafast Grignard addition reactions in the presence of water.
复制标题
有水存在下的超快格氏加成反应。
DOI：
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发表时间：
2010
影响因子：
3.2
通讯作者：
R. Madsen
中科院分区：
文献类型：
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作者：
Gyorgyi Osztrovszky;T. Holm;R. Madsen
研究了在质子试剂如水存在下烯丙基溴化镁和苄基氯化镁与羰基化合物的加成反应，发现羰基加成速率与质子化速率相当。
The addition of allylmagnesium bromide and benzylmagnesium chloride to carbonyl compounds was investigated in the presence of protic reagents such as water and the rate of carbonyl addition was found to be comparable to the rate of protonation by the reagent.