Equilibrium conformations of polymer chains Part II. Conformons in networks

Equilibrium conformations of polymer chains Part II. Conformons in networks
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聚合物链的平衡构象第二部分。

DOI:
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发表时间:
1986
期刊:
影响因子:
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通讯作者:
H. Kilian
H. Kilian
中科院分区:
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文献类型:
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作者:
T. Vilgis;H. Kilian

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对于理想网络,本文证明了N个非相互作用聚合物链的概念可以转化为橡胶弹性的非相互作用激发(称为共形子)问题。将永久交联上的相互作用建模为散射问题,并考虑到有限的链长,可以给出第二门尼系数的解释。有一些证据表明,结移动受约束的自扩散。
With regard to the ideal network it is shown that the concept ofN non-interacting polymer chains can be transformed in a problem of non interacting excitations (called conformons) for rubber elasticity. Modelling the interaction on permanent crosslinks as a scattering problem and taking the finite chain length into account, an interpretation of the second Mooney coefficient can be given. There is some evidence that the junctions move by constrained self diffusion.