Guest-induced instant and reversible crystal-to-crystal transformation of 1,4-bis(ferrocenylethynyl)anthraquinone
Guest-induced instant and reversible crystal-to-crystal transformation of 1,4-bis(ferrocenylethynyl)anthraquinone
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DOI：
10.1002/anie.200600933
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发表时间：
2006-01-01
影响因子：
16.6
通讯作者：
Sakata, Makoto
中科院分区：
文献类型：
--
作者：
Kondo, Mio;Murata, Masaki;Sakata, Makoto
（化学方程式）给体-受体（DA）化合物1，4-双（二茂铁乙炔基）蒽醌晶体形成多孔和无孔结构。引入客体的多孔和无客体的无孔结构可以通过客体分子的解吸和吸附瞬间可逆地互换，这导致一维柱状结构中DA和DAA排列的交替（见图）。
(Chemical Equation Presented) Both porous and nonporous structures are formed by crystals of donor-acceptor (DA) compound 1, 4-bis (ferrocenylethynyl) anthraquinone. The guest-incorporating porous and guest-free nonporous structures can interchange instantly and reversibly by desorption and adsorption of guest molecules, which cause alternation of DA and DAA arrangements in the one-dimensional columnar structure (see picture).