The Reactivity of 1,3,2-Diheterophospholans Containing a Tricoordinate Phosphorus Atom
The Reactivity of 1,3,2-Diheterophospholans Containing a Tricoordinate Phosphorus Atom
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含三配位磷原子的1,3,2-二杂磷烷的反应活性
DOI：
10.1070/rc1983v052n04abeh002823
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发表时间：
1983
影响因子：
7.7
通讯作者：
A. Pudovik
中科院分区：
文献类型：
--
作者：
M. Pudovik;V. Ovchinnikov;R. Cherkasov;A. Pudovik
对近年来含三配位磷原子的1，3，2-二杂磷杂环烷烃反应性的研究结果进行了评述。许多注意力已经投入到导致环磷原子的配位数增加的反应以及环外和环内取代反应。讨论了环磷化合物反应的机理和某些立体化学特征。在少数情况下，对反应性进行了定量估计。参考文献245篇。
The results of studies on the reactivity of 1,3,2-di-heterophosphacycloalkanes containing a tricoordinate phosphorus atom carried out in recent years are examined and surveyed. Much attention has been devoted to reactions leading to an increase of the coordination number of the ring phosphorus atom and also to exocyclic and endocyclic substitution reactions. The mechanisms and certain stereochemical characteristics of the reactions of cyclic phosphorus compounds are discussed. In a few instances the reactivities have been estimated quantitatively. The bibliography includes 245 references.