A new type of electrochemical oxidation of alcohols mediated with a rut henium-dioxolene-amine complex in neutral water
A new type of electrochemical oxidation of alcohols mediated with a rut henium-dioxolene-amine complex in neutral water
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中性水中钌-二氧杂环戊烯-胺络合物介导的新型醇电化学氧化
DOI：
10.1016/j.ica.2010.11.013
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发表时间：
2011
期刊：
影响因子：
--
通讯作者：
K.Tanaka
中科院分区：
文献类型：
--
作者：
H.Ozawa;T.Hini;H.Ohtsu;T.Wada;K.Tanaka
[RuII(Terpy)(Sq)(NH3)]+在中性水(pH 8.0)+0.8V(vs.SCE)中电化学氧化生成[RuII(Terpy)(Q)(Nh2)]2+和/或[RuIII(terpy)(sq)(NH2)]2+(terpy=2，2′：6′，2′′-terpyridine，sq=3，5-二叔丁基-1，2-半奎宁酸，q=3，5-二叔丁基-1，2-苯二酚)，在甲醇、乙醇和异丙醇的催化氧化中起到吸氢和单电子受体的作用，分别在电解条件下。
Electrochemical oxidation of [RuII(terpy)(sq)(NH3)]+in neutral water (pH 8.0) at +0.8V (versus SCE) generated [RuII(terpy)(q)(NH2)]2+and/or [RuIII(terpy)(sq)(NH2)]2+(terpy=2,2′:6′,2′′-terpyridine, sq=3,5-di-tert-butyl-1,2-semiquinonate, q=3,5-di-tert-butyl-1,2-benzoquinone), which played roles in hydrogen abstraction and one-electron acceptor in the catalytic oxidation of methanol, ethanol, and 2-propanol affording formaldehyde, acetoaldehyde, and acetone, respectively, under the electrolysis conditions.