Inside Back Cover: Hemilabile Ligands as Mechanosensitive Electrode Contacts for Molecular Electronics (Angew. Chem. Int. Ed. 46/2019)
Inside Back Cover: Hemilabile Ligands as Mechanosensitive Electrode Contacts for Molecular Electronics (Angew. Chem. Int. Ed. 46/2019)
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封底内页：半稳定配体作为分子电子学的机械敏感电极触点（Angew. Chem. Int. Ed. 46/2019）
DOI：
10.1002/anie.201913163
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发表时间：
2019
期刊：
影响因子：
--
通讯作者：
Ferri N
中科院分区：
文献类型：
--
作者：
Ferri N
。具有对外部刺激作出反应的电导的单实体连接点在分子电子学中特别令人感兴趣。通过应用均相催化、半稳定性的概念，以（2-甲硫基）噻吩封端的分子的电导（绿线）对其中一个电极（红线）位置的机械调制呈指数响应。这些机械驱动开关表现出高可逆性、速度和耐用性，为控制分子器件的电气特性提供了一种新的、稳健的方法。请阅读 A. Vezzolli、S. Sangtarash、CJ Lambert、SJ Higgins 及其同事撰写的研究文章（第 16583 页）了解更多信息。
. Single-entity junctions…… with conductance responsive to external stimuli are of particular interest in molecular electronics. By applying a concept from homogeneous catalysis, hemilability, molecules terminated with (2-methylthio) thiophene have conductance (green line) responding exponentially to mechanical modulations of the position of one of the electrodes (red line). These mechanically actuated switches showed high reversibility, speed and durability, offering a new, robust method to control the electrical properties of molecular devices. Read more in the Research Article by A. Vezzolli, S. Sangtarash, CJ Lambert, SJ Higgins, and co-workers on page 16583.