Revealing the photophysics of fac-[(dppz-12-NO2)Re(CO)3(4-Me2Npy)]+: a picosecond time-resolved IR study.

Revealing the photophysics of fac-[(dppz-12-NO2)Re(CO)3(4-Me2Npy)]+: a picosecond time-resolved IR study.
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揭示 fac-[(dppz-12-NO2)Re(CO)3(4-Me2Npy)] 的光物理学:皮秒时间分辨红外研究。

DOI:
10.1039/b200586g
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发表时间:
2002
影响因子:
4.9
通讯作者:
M. George
M. George
中科院分区:
化学2区
文献类型:
--
作者:
Joanne Dyer;D. Grills;P. Matousek;A. Parker;M. Towrie;J. Weinstein;M. George

文献摘要

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用皮秒时间分辨红外光谱研究了fac-[(dppz-12-NO2)Re(CO)3(4-Me 2Npy)]+在乙腈中的电子物理,首次发现了具有电荷分离最低激发态的Re(I)-dppz配合物.
The photophysics of fac-[(dppz-12-NO2)Re(CO)3(4-Me2Npy)]+ in CH3CN have been investigated using picosecond time-resolved IR (ps-TRIR) spectroscopy, to reveal the first example of a Re(I)-dppz complex with a charge separated lowest-lying excited state.