Doping-induced structure variation of 1,3-cyclohexane- bis(methylamine)-templated zinc-phosphorus open structures.
Doping-induced structure variation of 1,3-cyclohexane- bis(methylamine)-templated zinc-phosphorus open structures.
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DOI：
10.1021/ic701825m
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发表时间：
2008-01
影响因子：
4.6
通讯作者：
Yang Yang-Yang;Yongnan Zhao;Jianguo Yu;Shizhen Wu;Ruji J. Wang
中科院分区：
文献类型：
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作者：
Yang Yang-Yang;Yongnan Zhao;Jianguo Yu;Shizhen Wu;Ruji J. Wang
以1,3-环己烷-双甲胺(CHBMA)为模板，合成了具有超大20环通道的新型磷酸亚磷酸锌(TJPU-3)。钴掺杂产生了具有 12 环孔径的双金属亚磷酸盐 (TJPU-6)。虽然模板在 TJPU-3 中处于顺式配置，但在 TJPU-6 中处于反式配置。该结果具有分离和识别 CHBMA 异构体的潜力。
By using 1,3-cyclohexane-bis(methylamine) (CHBMA) as the template, a novel zinc phosphatophosphite (TJPU-3) with extra-large 20-ring channels was synthesized. Cobalt doping produced a bimetallic phosphite (TJPU-6) with 12-ring apertures. While the templates sit in the cis configuration in TJPU-3, they are in the trans configuration in TJPU-6. This result has the potential for separation and recognition of CHBMA isomers.