A single layered organic-inorganic hybrid compound [(FBMA)(2)PbBr4] with reversible phase transition and intense fluorescent property
A single layered organic-inorganic hybrid compound [(FBMA)(2)PbBr4] with reversible phase transition and intense fluorescent property
复制标题
具有可逆相变和强荧光特性的单层有机-无机杂化化合物[(FBMA)(2)PbBr4]
DOI：
10.1016/j.jssc.2018.11.012
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发表时间：
2019
影响因子：
3.3
通讯作者：
Cai Hu
中科院分区：
文献类型：
--
作者：
Hao Yanhuan;Wen Shuyao;Yao Jiaojiao;Wei Zhenhong;Zhang Xiuxiu;Jiang Zhentao;Mei Yingxuan;Cai Hu
Reactions of 3-fluoro-N-methylbenzylamine (FBMA) with PbBr2in concentrated HBr aqueous solution afforded a two-dimensional (2D) single layered organic-inorganic hybrid material [(FBMA)2PbBr4], which was confirmed by X-ray single crystal diffraction, infrared (IR) spectroscopy and powder X-ray diffraction (PXRD). The thermodynamic DSC analysis revealed it has a pair of reversible phase transition peaks with large thermal hysteresis exhibiting a first-order type phase transition. The variable-temperature single crystal diffraction proved the phase transition is originated from the order and disorder of organic-inorganic hybrid structures at room and high temperatures. Simultaneously compound [(FBMA)2PbBr4] exhibited a strong emission peak at 443 nm when under an excitation wavelength of 380 nm.
