A catalytic oxidative esterification of aldehydes using V2O5-H2O2

A catalytic oxidative esterification of aldehydes using V2O5-H2O2
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DOI:
10.1021/ol990383
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发表时间:
2000-03-09
期刊:
影响因子:
5.2
通讯作者:
Patel, BK
Patel, BK
中科院分区:
化学1区
文献类型:
--
作者:
Gopinath, R;Patel, BK

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[图表]在甲醇存在下,醛在用催化量的五氧化二钒与氧化剂过氧化氢组合处理后发生氧化转化为相应的酯。温和的反应条件、较短的反应时间、高效率、成本效益和所需产物的容易分离使本方法成为一种实用的替代方案。
[GRAPHICS]Aldehydes, in the presence of methanol, undergo oxidative transformation to the corresponding esters upon treatment with catalytic amounts of vanadium pentoxide in combination with oxidant hydrogen peroxide. Mild reaction conditions, shorter reaction times, high efficiencies, cost-effectiveness, and facile isolation of the desired products make the present methodology a practical alternative.