Methane storage in dry water gas hydrates

Methane storage in dry water gas hydrates
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DOI:
10.1021/ja8048173
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发表时间:
2008-09-03
影响因子:
15
通讯作者:
Cooper, Andrew I.
Cooper, Andrew I.
中科院分区:
化学1区
文献类型:
--
作者:
Wang, Weixing;Bray, Christopher L.;Cooper, Andrew I.

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干水在2.7 MPa和273.2 K下以水合物形式储存175 v(STP)/v甲烷,这接近能源部甲烷储存的体积目标。干水是二氧化硅稳定的自由流动的粉末(95%wt水),并且由于该材料的相对大的表面积与体积比,观察到快速的甲烷吸收(在160分钟内90%饱和吸收,没有混合)。
Dry water stores 175 v(STP)/v methane at 2.7 MPa and 273.2 K in a hydrate form which is close to the Department of Energy volumetric target for methane storage. Dry water is a silicastabilized free-flowing powder (95% wt water), and fast methane uptakes were observed (90% saturation uptake in 160 min With no mixing) as a result of the relatively large surface-to-volume ratio of this material.