Ionic liquids:: polar, but weakly coordinating solvents for the first biphasic oligomerisation of ethene to higher α-olefins with cationic Ni complexes
Ionic liquids:: polar, but weakly coordinating solvents for the first biphasic oligomerisation of ethene to higher α-olefins with cationic Ni complexes
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DOI：
10.1039/b101400p
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发表时间：
2001-01-01
影响因子：
4.9
通讯作者：
Dunkin, IR
中科院分区：
文献类型：
--
作者：
Wasserscheid, P;Gordon, CM;Dunkin, IR
与传统溶剂相比，离子液体中的乙烯齐聚主要产生具有更好的反应性和选择性的Alk-1-ene产物；循环频率与使用溶致变色染料获得的极性数据相关联。
Ethylene oligomerisation in ionic liquids gives predominately alk-1-ene products with better reactivity and selectivity than in conventional solvents; turnover frequencies are correlated with polarity data obtained using solvatochromic dyes.