Cover Feature: Planar‐Chiral Ferrocene‐Based N‐Heterocyclic Carbene Ligands (Chem. Eur. J. 70/2018)
Cover Feature: Planar‐Chiral Ferrocene‐Based N‐Heterocyclic Carbene Ligands (Chem. Eur. J. 70/2018)
复制标题
封面专题：平面手性二茂铁基 N-杂环卡宾配体 (Chem. Eur. J. 70/2018)
DOI：
10.1002/chem.201805458
复制
发表时间：
2018
期刊：
影响因子：
--
通讯作者：
Yasue Risa
中科院分区：
文献类型：
--
作者：
Yoshida Kazuhiro;Yasue Risa
二茂铁是一种典型的三明治结构化合物，自发现以来就引起了许多化学家的关注。以其独特的结构作为配体骨架在过渡金属催化中的应用是二茂铁化学的成功范例之一。氮杂环卡宾（NHC）配体具有不同于膦配体的特点，已成为配位化学中不可缺少的工具。二茂铁和NHC结构结合可以生成什么样的配体？本文以平面手性配体为研究对象，综述了世纪初这一领域的研究进展。更多信息可以在Minireview中找到。Yoshida和R.第18575页上的Yasue。
Ferrocene, a prototypical sandwich compound, has attracted the attention of many chemists since its discovery. The application of its unique structure as a ligand scaffold in transition-metal catalysis is one of the successful examples of ferrocene chemistry. N-heterocyclic carbene (NHC) ligands, which have characteristics different from phosphine ligands, have emerged to become an indispensable tool in coordination chemistry. What kind of ligand could be generated by combining ferrocene and NHC structures? Focusing on planar-chiral ligands, this article summarizes advances in the field, which started at the beginning of the century. More information can be found in the Minireview by K. Yoshida and R. Yasue on page 18575.