Low-Energy-Electron-Induced Hydroamination of an Alkene
Low-Energy-Electron-Induced Hydroamination of an Alkene
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DOI：
10.1002/anie.200901338
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发表时间：
2009-01-01
影响因子：
16.6
通讯作者：
Swiderek, Petra
中科院分区：
文献类型：
--
作者：
Hamann, Thorben;Boehler, Esther;Swiderek, Petra
最小催化剂：一种通过暴露于低能电子来控制化学合成的新策略依赖于由反应伙伴之一的软电离引起的静电吸引。这种方法被用来诱导C2H4和NH3之间的反应产生氨基乙烷。该反应类似于氢化胺化反应，除了电子束取代了有机合成中使用的催化剂。
The smallest catalyst: A new strategy to control chemical synthesis by exposure to low‐energy electrons relies on the electrostatic attraction caused by the soft ionization of one of the reaction partners. This approach was used to induce a reaction between C2H4and NH3yielding aminoethane. The reaction resembles a hydroamination except that the electron beam replaces the catalyst used in the organic synthesis.