Effect of substituent groups for formation of organic-metal hybrid nanowires by charge-transfer of tetrathiafulvalene derivatives with metal ion
Effect of substituent groups for formation of organic-metal hybrid nanowires by charge-transfer of tetrathiafulvalene derivatives with metal ion
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DOI：
10.1016/j.synthmet.2009.02.005
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发表时间：
2009-05-01
期刊：
影响因子：
4.4
通讯作者：
Chujo, Y.
中科院分区：
文献类型：
--
作者：
Naka, K.;Ando, D.;Chujo, Y.
研究了取代基对四硫富瓦烯(TTF)单元形成有机-金属杂化纳米线的影响。根据取代基团的不同，TTF衍生物与HAuCl4在室温的CH3CN溶液中，通过TTF衍生物与金离子之间的电子转移反应，得到了以沉淀形式存在的纳米线。为了有利于杂化纳米线的形成，需要增加平面性并在TTF衍生物上引入强相互作用。(C)2009爱思唯尔B.V.保留所有权利。
Effect of substituent groups on a tetrathiafulvalene (TTF) unit for formation of organic-metal hybrid nanowires was studied. Depend on the substituent groups, the nanowires were obtained as a precipitate just by mixing TTF derivatives and HAuCl4 in CH3CN Solution it room temperature via electron transfer reaction between the TTF derivatives and a gold ion. To precede favorably hybrid nanowire formation, increase planarity and introduction of strong interaction on the TTF derivatives are required. (C) 2009 Elsevier B.V. All rights reserved.