Selective formation of siloxane-based hybrid cages with methylene groups in the frameworks
Selective formation of siloxane-based hybrid cages with methylene groups in the frameworks
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DOI：
10.1039/b411794h
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发表时间：
2004-01-01
影响因子：
4.9
通讯作者：
Kuroda, K
中科院分区：
文献类型：
--
作者：
Shimojima, A;Kuroda, K
在四甲基氢氧化铵的存在下，通过对亚甲基桥式双烷氧基硅烷前驱体的水解和缩聚，选择性地形成了一类新的笼状低聚物，从而产生了新型硅基杂化材料。
A new class of cage-like oligomers were selectively formed by hydrolysis and polycondensation of a methylene-bridged bistrialkoxysilane precursor in the presence of tetramethylammonium hydroxide, which led to the creation of novel silica-based hybrid materials.