Enantioselective Symmetry Breaking Directed by the Order of Process Steps
Enantioselective Symmetry Breaking Directed by the Order of Process Steps
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DOI：
10.1002/anie.200907231
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发表时间：
2010-01-01
影响因子：
16.6
通讯作者：
Vlieg, Elias
中科院分区：
文献类型：
--
作者：
Noorduin, Wim L.;Meekes, Hugo;Vlieg, Elias
反过来：研磨引起的对称性破缺产物的构型可以简单地通过不同反应混合物组分的组合顺序来控制。潜在的机制基于对映选择性晶体生长和溶解之间的微妙平衡。
Going forward in reverse: The configuration of the product of grinding-induced symmetry breaking can be controlled simply by the order in which the different reaction-mixture components are combined. The underlying mechanism is based on a subtle balance between enantioselective crystal growth and dissolution.