Reduction of allylpalladium(II)chloride dimer by formation of allyloxysilanes
Reduction of allylpalladium(II)chloride dimer by formation of allyloxysilanes
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DOI：
10.1055/s-2006-951516
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发表时间：
2006-11-03
期刊：
影响因子：
2
通讯作者：
Smith, Russell C.
中科院分区：
文献类型：
--
作者：
Denmark, Scott E.;Smith, Russell C.
烯丙基钯(II)氯化物二聚体(APC)与碱金属硅烷酸酯反应可将其还原为Pd(0)物种。在存在螯合型双膦配体和各种硅烷酸酯的情况下，还原速度极快。
The reduction of allylpalladium(II)chloride dimer (APC) to a Pd(0) species can be effected by reaction with alkali metal silanolates. The reduction is extremely rapid in the presence of chelating bisphosphine ligands and for a variety of silanolates.