Characterization of synthetic gasoline from the chloromethane-zeolite reaction
Characterization of synthetic gasoline from the chloromethane-zeolite reaction
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DOI：
10.1021/ef00031a012
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发表时间：
1992
期刊：
影响因子：
5.3
通讯作者：
C. M. White;L. Douglas;J. Hackett;R. Anderson
中科院分区：
文献类型：
--
作者：
C. M. White;L. Douglas;J. Hackett;R. Anderson
用高分辨气相色谱结合质谱仪或傅里叶变换红外光谱对氯甲烷与沸石反应的产物进行了表征。含四个碳及以下的碳氢化合物气体约占总产品的53wt%。浓缩液体产品约占产品的47wt%。用气相色谱从浓缩液体产物中分析分离出240多种化合物，鉴定出约占浓缩液体产物重量%的106种化合物。非环烷烃、环烷烃和烯烃以及芳香烃构成了凝析液体产品的大部分，其中含有碳数最多为13的化合物。
products from the reaction of chloromethane with a zeolite have been characterized using high-resolution gas chromatography combined with either mass spectrometry or Fourier transform infrared spectroscopy. Hydrocarbon gases having four carbons and less were about 53 wt% of the total product. A condensed liquid product constituted about 47 wt% of the product. Over 240 compounds were analytically separated from the condensed liquid product by gas chromatography, allowing the identification of 106 products that constituted about 89 wt% of the condensed liquid product. Acyclic and cyclic alkanes and olefins, as well as aromatics, make up the majority of the condensed liquid product, which contained compounds having carbon numbers up to 13