A Practical Synthesis of Azobenzenes through Oxidative Dimerization of Aromatic Amines Using tert-Butyl Hypoiodite
A Practical Synthesis of Azobenzenes through Oxidative Dimerization of Aromatic Amines Using tert-Butyl Hypoiodite
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DOI：
10.1055/s-0032-1318388
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发表时间：
2013-03
期刊：
影响因子：
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通讯作者：
Y. Takeda;Sota Okumura;S. Minakata
中科院分区：
文献类型：
--
作者：
Y. Takeda;Sota Okumura;S. Minakata
摘要本文介绍了一种简单、方便、有效的偶氮苯的合成方法，该方法采用一种独特的碘化试剂，通过芳香胺的氧化二聚反应合成偶氮苯。这种新方法允许在非常温和的条件下容易地获得对称和不对称偶氮苯。
Abstract A straightforward, convenient, and efficient synthetic method of azobenzenes through oxidative dimerization of aromatic amines using a unique and cost-effective iodinating reagent is described. This new method allows for easy access to both of symmetrical and unsymmetrical azobenzenes under extremely mild conditions.